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Isebenza njani i-polycarboxylate superplastisizer kudaka lwesamente?

Uphuhliso kunye nokusetyenziswa kwepolycarboxylic superplasticizerikhawuleza ngokwentelekiso. Ngokukodwa kwiiprojekthi ezinkulu kunye nezingundoqo ezifana nokugcinwa kwamanzi, amandla ombane, ubunjineli behydraulic, ubunjineli baselwandle, kunye neebhulorho, i-polycarboxylate superplastisizer isetyenziswa ngokubanzi.

Emva kokuba i-samente ixutywe namanzi, i-cement slurry yenza isakhiwo se-flocculation ngenxa ye-gravity ye-molecular of the particles ye-cement, ukwenzela ukuba i-10% ukuya kwi-30% yamanzi okuxuba ihlanganiswe kwiincinci zesamente kwaye ayinakuthatha inxaxheba ekuhambeni kwamahhala kunye ne-lubrication, ngaloo ndlela ichaphazela i-Flowability yomxube wekhonkrithi. Xa i-supreplasticizer yongezwa, iimolekyuli ze-agent yokunciphisa amanzi zinokubhengezwa kwinqanaba leengqungquthela ze-samente, ukwenzela ukuba iindawo zeengqungquthela zesamente zibe nentlawulo efanayo (ngokuqhelekileyo intlawulo engalunganga), yenze i-electrostatic repulsion, ekhuthaza ukusasazeka ngokubambisana kweengqungquthela zesamente kunye nokutshatyalaliswa kwesakhiwo se-samente. , ukukhulula inxalenye yamanzi asongiweyo ukuba athathe inxaxheba ekuhambeni, ngaloo ndlela ukwandisa ngokufanelekileyo umbane womxube wekhonkrithi.

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Iqela le-hydrophilic kwii-arhente yokunciphisa amanzii-polar kakhulu, ngoko ke ifilimu ye-adsorption ye-agent yokunciphisa amanzi kumphezulu wamasuntswana e-samente ingenza ifilimu ezinzileyo yamanzi edibeneyo kunye ne-molecule yamanzi. Le filimu yamanzi inefuthe elihle lokuthambisa kwaye inokunciphisa ngokufanelekileyo ukuxhatshazwa kwe-sliding phakathi kweengqungquthela zesamente, ngaloo ndlela iphucula ngakumbi umbane wodaka kunye nekhonkrithi.

Ikhonkco le-hydrophilic branched kwisuperplasticizerUlwakhiwo lunwebeka kwisisombululo esinamanzi, ngaloo ndlela senza umaleko we-hydrophilic-dimensional adsorption kunye nobukhulu obuthile kumphezulu wamasuntswana e-samente adsorbed. Xa iinqununu ze-samente zisondele komnye nomnye, i-adsorption layers iqala ukugqithisa, oko kukuthi, ukuphazamiseka kwe-steric kwenzeka phakathi kweengqungquthela ze-samente. Ukugqithisa okungaphezulu, ukunyanzeliswa okukhulu kwe-steric, kunye nokuphazamiseka okukhulu kokubambisana phakathi kweengqungquthela zesamente, okwenza udaka kunye nekhonkrithi I-Slump ihlala ilungile.

Ngexesha lokulungiselela inkqubo yei-agent yokunciphisa amanzi e-polycarboxylate, ezinye iintambo ezinamagatsha zixutywe kwiimolekyuli ze-agent yokunciphisa amanzi. Le khonkco ye-branched ayinikezeli kuphela umphumo wokuthintela i-steric, kodwa kwakhona, kwindawo ephezulu ye-alkalinity ye-cement hydration, Ikhonkco yesebe inokuthi inqunyulwe ngokukhawuleza, ngaloo ndlela ikhulule i-polycarboxylic acid ene-dispersing effect, enokuphucula umphumo wokusabalalisa amasuntswana e-samente kunye nokulawula ukulahleka kwe-slump.


Ixesha lokuposa: Mar-29-2024